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Efecto de la morfología de la película

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Efecto de la morfología de la película [ editar ]

Fig. 8: Heterounión muy plegada (a); heterounión con crecimiento controlado (b)

Como se describió anteriormente, las heterouniones dispersasde materiales orgánicos donantes-aceptores tienen eficiencias cuánticas altas en comparación con la heterounión plana, porque en las heterouniones dispersas es más probable que un excitón encuentre una interfaz dentro de su longitud de difusión. La morfología de la película también puede tener un efecto drástico en la eficiencia cuántica del dispositivo. Las superficies rugosas y la presencia de huecos pueden aumentar la resistencia en serie y también la posibilidad de cortocircuito. La morfología de la película y, como resultado, la eficiencia cuántica se pueden mejorar recociendo un dispositivo después de cubrirlo con un cátodo de metal de ~1000 Å de espesor. La película de metal encima de la película orgánica aplica tensiones sobre la película orgánica, lo que ayuda a prevenir la relajación morfológica en la película orgánica.[99]

Heterounión de crecimiento controlado [ editar ]

La separación de carga se produce en la interfaz donante-aceptor. Mientras viaja hacia el electrodo, una carga puede quedar atrapada y/o recombinarse en un material orgánico interpenetrante desordenado, lo que resulta en una disminución de la eficiencia del dispositivo. El crecimiento controlado de la heterounión proporciona un mejor control sobre las posiciones de los materiales donantes-aceptores, lo que da como resultado una eficiencia energética mucho mayor (relación entre la potencia de salida y la potencia de entrada) que la de las heterouniones planas y altamente desorientadas (como se muestra en la Fig. 8) . Por lo tanto, la elección de parámetros de procesamiento adecuados para controlar mejor la estructura y la morfología de la película es muy deseable. [32]

Avances en las técnicas de crecimiento 

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